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Applied Physics and Mathematics

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The description of spin in the language of quaternion algebra
M.A. Mikaelyan

In non-relativistic quantum mechanics the particle with spin ½ is
associated with the evolution of four real functions, which combine
with each other in two complex functions that form a spinor.
With the help of quaternion algebra an alternative variant of
combining in one quaternion function was considered [1,2]. Ultimately
a description of spin particle appears to be identical to
the description of spinless particle; in all formulas instead of the
usual imaginary unit the quaternion imaginary unit figures. At
the same time, unlike standard description, «switching» of magnetic
field by the use of well-known substitution in momentum
operator leads to the correct value of intrinsic magnetic moment
of the particle. Previously [1,3] the relativistic generalization
of the description of spin particle has been formulated and
corresponds to the usage of biquaternion algebra (biquaternion
is a quaternion with complex components). As in non-relativistic
case the wave function is a one-component quantity. It means
an absence of matrices in the formalism; this fact considerably
simplifies the consideration. In this article the more detailed
consideration is presented. In particular, it is shown that the use
of complex quaternion algebra allows (without the turning to
Dirac equation) to obtain the wave equation, which is identical
to Klein-Gordon equation. At the same time such an equation
automatically takes into account the «direct» interaction between
spin and the electromagnetic field. Significant attention
in the article is given to the technical issues – in particular, to the
obtaining the rules of the conversion from the quaternion to the
traditional description.
Keywords: quantum mechanics, spin, quaternion, biquaternion,
Pauli equation, Dirac equation.

Contacts: E-mail: mikhail@bk.ru

Pp. 72-85.

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